Total ionic strength adjustment buffers (TISAB) are buffer solutions that increase the ionic strength of a solution to a relatively high level. This is important for potentiometric measurements, including ion-selective electrodes, because they measure the activity of the analyte rather than its concentration. TISAB is very commonly applied to fluoride ion analysis such as in fluoride ion-selective electrodes. Each constituent of TISAB plays an important role in controlling the ionic strength and pH of the analyte solution.

VWR® TISAB II Solution (Total Ionic Strength Adjustment Buffer) for Fluoride Determinations

Supplier: VWR Chemicals

Total ionic strength adjustment buffer solution for use with selective ion electrodes.

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TISAB III solution (Total Ionic Strength Adjustment Buffer) for fluoride determinations

Supplier: Mettler - Toledo

TISAB III solution for fluoride determinations

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Fluoride buffer solution According to DEV D4, Fluka™

Supplier: Honeywell Chemicals

TISAB according to DEV D4.

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ISE sample conditioning buffers and solutions

Supplier: WTW

Ion strength adjustment solutions have multiple tasks: TISAB for fluoride measurements does not only adjust the pH value, by also decomplexes the fluoride-containing complex compounds. Other ion strength adjustment solutions ensure an adapted pH value as well as the addition of a suitable conducting salt to correctly capture the concentration.